Yes, you can, the northern part of the compass needle will indicate a plus.
The compass will respond to a magnetic field that forms around a conductor through which electric current flows. Therefore, when the battery is disconnected from the consumer, the current does not flow. In order to determine the direction of electron motion (and hence the polarity of the current source), it is necessary to connect a consumer designed for the voltage of this battery (the consumer can be a conventional incandescent lamp, which does not require observing the polarity of the power source). Accordingly, in this case, it will be possible to determine where plus and where minus using a compass.
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